radical_chemistry

Dual Photoredox/Nickel-Catalyzed Conversion of Aryl Halides to Aryl Aminooxetanes: Computational Evidence for a Substrate-Dependent Switch in Mechanism

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  • K. Kolahdouzan, R. Khalaf, J.M. Grandner, Y. Chen, J.A. Terrett, and M.P. Huestis, "Dual Photoredox/Nickel-Catalyzed Conversion of Aryl Halides to Aryl Aminooxetanes: Computational Evidence for a Substrate-Dependent Switch in Mechanism", ACS Catalysis, vol. 10, pp. 405-411, 2019. http://dx.doi.org/10.1021/acscatal.9b03596
  • Photoredox-Mediated Minisci C–H Alkylation Reactions between N-Heteroarenes and Alkyl Iodides with Peroxyacetate as a Radical Relay Initiator

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  • Z. Wang, J. Dong, Y. Hao, Y. Li, Y. Liu, H. Song, and Q. Wang, "Photoredox-Mediated Minisci C–H Alkylation Reactions between N-Heteroarenes and Alkyl Iodides with Peroxyacetate as a Radical Relay Initiator", The Journal of Organic Chemistry, vol. 84, pp. 16245-16253, 2019. http://dx.doi.org/10.1021/acs.joc.9b02848
  • Open-Shell Fluorination of Alkyl Bromides: Unexpected Selectivity in a Silyl Radical-Mediated Chain Process

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  • G.H. Lovett, S. Chen, X. Xue, K.N. Houk, and D.W.C. MacMillan, "Open-Shell Fluorination of Alkyl Bromides: Unexpected Selectivity in a Silyl Radical-Mediated Chain Process", Journal of the American Chemical Society, vol. 141, pp. 20031-20036, 2019. http://dx.doi.org/10.1021/jacs.9b11434
  • Direct Use of Carboxylic Acids in the Photocatalytic Hydroacylation of Styrenes To Generate Dialkyl Ketones

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  • J.I. Martinez Alvarado, A.B. Ertel, A. Stegner, E.E. Stache, and A.G. Doyle, "Direct Use of Carboxylic Acids in the Photocatalytic Hydroacylation of Styrenes To Generate Dialkyl Ketones", Organic Letters, vol. 21, pp. 9940-9944, 2019. http://dx.doi.org/10.1021/acs.orglett.9b03871
  • Olefin Amine (OLA) Reagents for the Synthesis of Bridged Bicyclic and Spirocyclic Saturated N-Heterocycles by Catalytic Hydrogen Atom Transfer (HAT) Reactions


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  • Y. Wang, and J.W. Bode, "Olefin Amine (OLA) Reagents for the Synthesis of Bridged Bicyclic and Spirocyclic Saturated N-Heterocycles by Catalytic Hydrogen Atom Transfer (HAT) Reactions", Journal of the American Chemical Society, vol. 141, pp. 9739-9745, 2019. http://dx.doi.org/10.1021/jacs.9b05074
  • A Radical Approach to Anionic Chemistry: Synthesis of Ketones, Alcohols, and Amines

    [Baran lab]
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  • S. Ni, N.M. Padial, C. Kingston, J.C. Vantourout, D.C. Schmitt, J.T. Edwards, M.M. Kruszyk, R.R. Merchant, P.K. Mykhailiuk, B.B. Sanchez, S. Yang, M.A. Perry, G.M. Gallego, J.J. Mousseau, M.R. Collins, R.J. Cherney, P.S. Lebed, J.S. Chen, T. Qin, and P.S. Baran, "A Radical Approach to Anionic Chemistry: Synthesis of Ketones, Alcohols, and Amines", Journal of the American Chemical Society, vol. 141, pp. 6726-6739, 2019. http://dx.doi.org/10.1021/jacs.9b02238
  • Deaminative Reductive Cross-Electrophile Couplings of Alkylpyridinium Salts and Aryl Bromides

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  • J. Liao, C.H. Basch, M.E. Hoerrner, M.R. Talley, B.P. Boscoe, J.W. Tucker, M.R. Garnsey, and M.P. Watson, "Deaminative Reductive Cross-Electrophile Couplings of Alkylpyridinium Salts and Aryl Bromides", Organic Letters, vol. 21, pp. 2941-2946, 2019. http://dx.doi.org/10.1021/acs.orglett.9b01014