organomet_chem

Visible‐Light‐Promoted Iron‐Catalyzed C(sp2)–C(sp3) Kumada Cross‐Coupling in Flow

[Timothy Noel]

[1]

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  • Sodium Methyl Carbonate as an Effective C1 Synthon. Synthesis of Carboxylic Acids, Benzophenones, and Unsymmetrical Ketones


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  • T.E. Hurst, J.A. Deichert, L. Kapeniak, R. Lee, J. Harris, P.G. Jessop, and V. Snieckus, "Sodium Methyl Carbonate as an Effective C1 Synthon. Synthesis of Carboxylic Acids, Benzophenones, and Unsymmetrical Ketones", Organic Letters, vol. 21, pp. 3882-3885, 2019. http://dx.doi.org/10.1021/acs.orglett.9b00773
  • Use of the 2-Pyridinesulfonyloxy Leaving Group for the Fast Copper-Catalyzed Coupling Reaction at Secondary Alkyl Carbons with Grignard Reagents

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  • Gram-Scale, Cheap, and Eco-Friendly Iron-Catalyzed Cross-Coupling between Alkyl Grignard Reagents and Alkenyl or Aryl Halides

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  • G. Cahiez, G. Lefèvre, A. Moyeux, O. Guerret, E. Gayon, L. Guillonneau, N. Lefèvre, Q. Gu, and E. Zhou, "Gram-Scale, Cheap, and Eco-Friendly Iron-Catalyzed Cross-Coupling between Alkyl Grignard Reagents and Alkenyl or Aryl Halides", Organic Letters, vol. 21, pp. 2679-2683, 2019. http://dx.doi.org/10.1021/acs.orglett.9b00665
  • Reaction of Nitrogen‐Radicals with Organometallics Under Ni‐Catalysis: N‐Arylations and Amino‐Functionalization Cascades

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  • Rhodium-Catalyzed Aldehyde Arylation via Formate-Mediated Transfer Hydrogenation: Beyond Metallic Reductants in Grignard/Nozaki–Hiyami–Kishi-Type Addition

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  • R.A. Swyka, W. Zhang, J. Richardson, J.C. Ruble, and M.J. Krische, "Rhodium-Catalyzed Aldehyde Arylation via Formate-Mediated Transfer Hydrogenation: Beyond Metallic Reductants in Grignard/Nozaki–Hiyami–Kishi-Type Addition", Journal of the American Chemical Society, vol. 141, pp. 1828-1832, 2019. http://dx.doi.org/10.1021/jacs.8b13652