sulfur_chemistry

RASS‐Enabled S/P–C and S–N Bond Formation for DEL Synthesis

Flood, Baran, Dawson et al.

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  • D.T. Flood, X. Zhang, X. Fu, Z. Zhao, S. Asai, B.B. Sanchez, E.J. Sturgell, J.C. Vantourout, P. Richardson, M.E. Flanagan, D.W. Piotrowski, D.K. Kölmel, J. Wan, M. Tsai, J.S. Chen, P.S. Baran, and P.E. Dawson, "RASS‐Enabled S/P−C and S−N Bond Formation for DEL Synthesis", Angewandte Chemie, vol. 132, pp. 7447-7453, 2020. http://dx.doi.org/10.1002/ange.201915493
  • Increasing Complexity: A Practical Synthetic Approach to Three‐Dimensional, Cyclic Sulfoximines and First Insights into Their in vitro Properties

    Bayer:

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  • E. Boulard, V. Zibulski, L. Oertel, P. Lienau, M. Schäfer, U. Ganzer, and U. Lücking, "Increasing Complexity: A Practical Synthetic Approach to Three‐Dimensional, Cyclic Sulfoximines and First Insights into Their in Vitro Properties", Chemistry – A European Journal, vol. 26, pp. 4378-4388, 2020. http://dx.doi.org/10.1002/chem.201905461
  • Studies of Halogen Bonding Induced by Pentafluorosulfanyl Aryl Iodides: A Potential Group of Halogen Bond Donors in a Rational Drug Design

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  • . Sumii, . Sasaki, . Tsuzuki, and . Shibata, "Studies of Halogen Bonding Induced by Pentafluorosulfanyl Aryl Iodides: A Potential Group of Halogen Bond Donors in a Rational Drug Design", Molecules, vol. 24, pp. 3610, 2019. http://dx.doi.org/10.3390/molecules24193610
  • Site‐Selective, Modular Diversification of Polyhalogenated Aryl Fluorosulfates (ArOSO2F) Enabled by an Air‐Stable Pd(I) Dimer

    Very interesting solvent effect described by Schoenebeck, making it possible to selectively couple @ C-Br, then @ C-OSO2F, and finally @ C-Cl bonds on a range of substrates.
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  • M. Mendel, I. Kalvet, D. Hupperich, G. Magnin, and F. Schoenebeck, "Site‐Selective, Modular Diversification of Polyhalogenated Aryl Fluorosulfates (ArOSO 2 F) Enabled by an Air‐Stable Pd I Dimer", Angewandte Chemie International Edition, vol. 59, pp. 2115-2119, 2020. http://dx.doi.org/10.1002/anie.201911465
  • Optimization and Gram-Scale Preparation of S-Trifluoromethyl Sulfoximines and Sulfilimino Iminiums, Powerful Reagents for the Late Stage Introduction of the CF3 Group

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  • A. Barthelemy, V. Certal, G. Dagousset, E. Anselmi, L. Bertin, L. Fabien, B. Salgues, P. Courtes, C. Poma, Y. El-Ahmad, and E. Magnier, "Optimization and Gram-Scale Preparation of S-Trifluoromethyl Sulfoximines and Sulfilimino Iminiums, Powerful Reagents for the Late Stage Introduction of the CF3 Group", Organic Process Research & Development, vol. 24, pp. 704-712, 2019. http://dx.doi.org/10.1021/acs.oprd.9b00403
  • Cyclic Alkenylsulfonyl Fluorides: Palladium‐Catalyzed Synthesis and Functionalization of Compact Multifunctional Reagents

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  • T.S. Lou, S.W. Bagley, and M.C. Willis, "Cyclic Alkenylsulfonyl Fluorides: Palladium‐Catalyzed Synthesis and Functionalization of Compact Multifunctional Reagents", Angewandte Chemie International Edition, vol. 58, pp. 18859-18863, 2019. http://dx.doi.org/10.1002/anie.201910871
  • Intramolecular Homolytic Substitution Enabled by Photoredox Catalysis: Sulfur, Phosphorus, and Silicon Heterocycle Synthesis from Aryl Halides


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  • A.F. Garrido-Castro, N. Salaverri, M.C. Maestro, and J. Alemán, "Intramolecular Homolytic Substitution Enabled by Photoredox Catalysis: Sulfur, Phosphorus, and Silicon Heterocycle Synthesis from Aryl Halides", Organic Letters, vol. 21, pp. 5295-5300, 2019. http://dx.doi.org/10.1021/acs.orglett.9b01911