formation of a highly polarized, aminium radical cation enables direct C–H amination, allowing the coupling of an exceptionally broad range of alkyl amines and arenes
[1]

  • A. Ruffoni, F. Juliá, T..D. Svejstrup, A..J. McMillan, J..J. Douglas, and D. Leonori, "Practical and regioselective amination of arenes using alkyl amines", Nature Chemistry, vol. 11, pp. 426-433, 2019. http://dx.doi.org/10.1038/s41557-019-0254-5
  • [1]

  • C. Denis, M.A.J. Dubois, A.S. Voisin-Chiret, R. Bureau, C. Choi, J.J. Mousseau, and J.A. Bull, "Synthesis of 3,3-Diarylazetidines by Calcium(II)-Catalyzed Friedel–Crafts Reaction of Azetidinols with Unexpected Cbz Enhanced Reactivity", Organic Letters, vol. 21, pp. 300-304, 2018. http://dx.doi.org/10.1021/acs.orglett.8b03745

  • [1]

  • C.P. Johnston, T.H. West, R.E. Dooley, M. Reid, A.B. Jones, E.J. King, A.G. Leach, and G.C. Lloyd-Jones, "Anion-Initiated Trifluoromethylation by TMSCF3: Deconvolution of the Siliconate–Carbanion Dichotomy by Stopped-Flow NMR/IR", Journal of the American Chemical Society, vol. 140, pp. 11112-11124, 2018. http://dx.doi.org/10.1021/jacs.8b06777
  • from the Scott E. Denmark group

    [1]

  • A.A. Thomas, A.F. Zahrt, C.P. Delaney, and S.E. Denmark, "Elucidating the Role of the Boronic Esters in the Suzuki–Miyaura Reaction: Structural, Kinetic, and Computational Investigations", Journal of the American Chemical Society, vol. 140, pp. 4401-4416, 2018. http://dx.doi.org/10.1021/jacs.8b00400
  • from the Scott E. Denmark group

    [1]

  • A.A. Thomas, H. Wang, A.F. Zahrt, and S.E. Denmark, "Structural, Kinetic, and Computational Characterization of the Elusive Arylpalladium(II)boronate Complexes in the Suzuki–Miyaura Reaction", Journal of the American Chemical Society, vol. 139, pp. 3805-3821, 2017. http://dx.doi.org/10.1021/jacs.6b13384