mechanism

Readily accessible sp3-rich cyclic hydrazine frameworks exploiting nitrogen fluxionality

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highlighted in www.chemistryworld.com/news/synthetic-strategy-exploits-fluxional-nitrogen-to-deliver-three-chiral-centres-for-the-price-of-one/4011029.article

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  • C. Dean, S. Rajkumar, S. Roesner, N. Carson, G.J. Clarkson, M. Wills, M. Jones, and M. Shipman, "Readily accessible sp3-rich cyclic hydrazine frameworks exploiting nitrogen fluxionality", Chemical Science, vol. 11, pp. 1636-1642, 2020. http://dx.doi.org/10.1039/C9SC04849A
  • A Method for the Catalytic Enantioselective Synthesis of Chiral a-Azido and a-Amino Ketones from Racemic a-Bromo Ketones, and Its Generalization to the Formation of Bonds to C, O, and S

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  • R. da Silva Gomes, and E.J. Corey, "A Method for the Catalytic Enantioselective Synthesis of Chiral α-Azido and α-Amino Ketones from Racemic α-Bromo Ketones, and Its Generalization to the Formation of Bonds to C, O, and S", Journal of the American Chemical Society, vol. 141, pp. 20058-20061, 2019. http://dx.doi.org/10.1021/jacs.9b12315
  • Unusual Electronic Effects of Ancillary Ligands on the Perfluoroalkylation of Aryl Iodides and Bromides Mediated by Copper(I) Pentafluoroethyl Complexes of Substituted Bipyridines

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  • E.D. Kalkman, M.G. Mormino, and J.F. Hartwig, "Unusual Electronic Effects of Ancillary Ligands on the Perfluoroalkylation of Aryl Iodides and Bromides Mediated by Copper(I) Pentafluoroethyl Complexes of Substituted Bipyridines", Journal of the American Chemical Society, vol. 141, pp. 19458-19465, 2019. http://dx.doi.org/10.1021/jacs.9b10540
  • Direct Use of Carboxylic Acids in the Photocatalytic Hydroacylation of Styrenes To Generate Dialkyl Ketones

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  • J.I. Martinez Alvarado, A.B. Ertel, A. Stegner, E.E. Stache, and A.G. Doyle, "Direct Use of Carboxylic Acids in the Photocatalytic Hydroacylation of Styrenes To Generate Dialkyl Ketones", Organic Letters, vol. 21, pp. 9940-9944, 2019. http://dx.doi.org/10.1021/acs.orglett.9b03871